Enhanced capacity retention of NCM batteries through doping optimization
DOI:
https://doi.org/10.62051/s8eysb66Keywords:
NCM battery, capacity retention, dopants.Abstract
Nowadays, People are very concerned about the range of electric vehicles, and scientists are also working hard to study how to increase the range. At present, among various methods to enhance energy density, replacing electrode materials is the most common. For instance, nickel get high capacity, the most common nickel-containing battery is NCM (LiNixCoyMnzO2) battery. During the charging and discharging process of NCM batteries, lattice distortion is prone to occur, leading to the collapse of the layered structure and the generation of microcracks. By doping large-radius ions to support the lattice structure, phase transition is suppressed and stress accumulation is reduced. Herein, among several solutions, the doping methods are analyzed emphatically. By consulting literature, based on XRD and other images, various doped elements are analyzed, and the retention rates of capacitance is analyzed to theoretically verify the bias of NCM on doped elements. This paper also proposes a hypothetical combination of doping methods and nanotechnology, aiming to address the expansion of some doped elements, such as silicon, through the characteristics of nanometers.
Downloads
References
[1] D.-H. Kim, J.-H. Song, C.-H. Jung, et al. Stepwise Dopant Selection Process for High-Nickel Layered Oxide Cathodes. Adv. Energy Mater., 2022, 12: 2200136.
[2] Shengxian She, Yangfan Zhou, Zijian Hong, et al, Surface Coating of NCM-811 Cathode Materials with g-C3N4 for Enhanced Electrochemical Performance, ACS Omega, 2022, 7(28), 24851-24857.
[3] Jiale Wang, Chengjin Liu, Qing Wang, et al, Investigation of W6+-doped in high-nickel LiNi0.83Co0.11Mn0.06O2 cathode materials for high-performance lithium-ion batteries, Journal of Colloid and Interface Science, 2022, 628, 338-349.
[4] K. Goharshadi, S.M. Masoudpanah, H. Nasrinpour, et al, Effects of Ba dopant on the structural, microstructural, and electrochemical properties of NCM811 cathode material (BaxLi1−xNi0.8Co0.1Mn0.1O2) for Li-i on storage, Electrochemistry Communications, 2025, 172, 107878,
[5] Dongyang Li, Wenbo Liu, Wenyu Liang, et al, Degradation mechanisms and modification strategies of nickel-rich NCM cathode in lithium-ion batteries, Mater. Res. Express, 2024, 11, 012006.
[6] Liga Britala, Mario Marinaro, Gints Kucinskis, et al. A review of the degradation mechanisms of NCM cathodes and corresponding mitigation strategies, Journal of Energy Storage, 2023, 73, 108875.
[7] Xu, J., Lin, F., Doeff, M. M., et al, A review of Ni-based layered oxides for rechargeable Li-ion batteries. Journal of Materials Chemistry A, 2020, 120(15), 874-902.
[8] K. Goharshadi, S.M. Masoudpanah, H. Nasrinpour, et al. Electrochemical performance of Sr-doped NCM 811 (SrxLi1-xNi0.8Co0.1Mn0.1O2) material for Li-ion storage, Materials Science and Engineering: B, 2025, 313, 117962.
[9] Sim, SJ., Lee, SH., Jin, BS. et al. Improving the electrochemical performances using a V-doped Ni-rich NCM cathode. Sci Rep, 2019, 9, 8952.
[10] Xiaoyong Yang, Shiyu Hou, Deping Xu, et al, Nano-silicon embedded in mildly-exfoliated graphite for lithium-ion battery anode materials, Advanced Powder Technology, 2024, 5, 104463.
[11] Seyed Shahabeddin Mirsasaani, Mehran Hemati, Tina Tavasoli, et al, Nanotechnology and Nanobiomaterials in Dentistry, Nanobiomaterials in Clinical Dentistry, 2013, 2, 17-33.
[12] Zhongyuan Luo, Huan Li, Weigang Wang, et al. Mitigating irreversible phase transition of Y-doped LiNi0.925Co0.03Mn0.045O2 by lattice engineering, Ceramics International, 2024, 50, 9535-9547.
Downloads
Published
Issue
Section
License
Copyright (c) 2025 Transactions on Environment, Energy and Earth Sciences

This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.









